Apply the load (orange arrow) at angle φ to the rectangular section and the neutral axis (cyan line) tilts by angle α. Colour shows the bending stress (blue = compression / red = tension). The circle marks the most-stressed corner.
$$\sigma=\frac{M_z\,y}{I_z}+\frac{M_y\,z}{I_y}$$
Stress in unsymmetric bending. Mz and My are the strong- and weak-axis components of the moment, Iz and Iy are the second moments of area, and y, z are the coordinates of the point. For a rectangle the product of inertia is zero, so this is a simple biaxial superposition.
$$\tan\alpha=\frac{M_y\,I_z}{M_z\,I_y}, \qquad I_z=\frac{b\,h^{3}}{12}, \quad I_y=\frac{h\,b^{3}}{12}$$
Neutral-axis tilt α and the second moments of area of a rectangle. When Iz ≠ Iy the neutral axis tilts away from the load plane.
$$\tan\beta=\frac{M_y/I_y}{M_z/I_z}$$
Deflection-direction angle β. Because curvature is proportional to M/I, β does not equal the load angle φ when Iz ≠ Iy.